Polyhedron Laboratories performs
molecular weight testing according to ASTM standards, such as Gel
Permeation Chromatography (ASTM D5296-05), Inherent Viscosity (ASTM
D1601-99), Inherent Viscosity (ASTM D4603-03) Dilute Solution
Viscosity (ASTM D1243-95) and Laser Light Scattering (multi-angle,
ASTM D4001-93). All ASTM standard descriptions below are paraphrased
from the ASTM website (www.astem.org). Due to copyright restrictions, Polyhedron
Laboratories cannot make available copies of standards.
Standards can be found and are available at www.astem.org.
ASTM D5296-05 Standard Test Method for
Molecular Weight Averages and Molecular Weight Distribution of
Polystyrene by High Performance Size-Exclusion Gel Permeation Chromatography - This
test procedure deals with the determination of molecular weight
averages and the distribution of molecular weights for linear,
soluble polymers by liquid high-performance size-exclusion
chromatography (HPSEC). This test procedure method calls for the use
of commercially available narrow molecular weight distribution (MWD)
polystyrene standards for calibration. This test procedure is valid
for specimens containing molecular weight components that have
elution volumes falling within the range defined by polystyrene
standards.
ASTM D1601-99 Standard
Test Method for Dilute Solution Viscosity of Ethylene Polymers -
This test procedure deals with the determination of the dilute
solution viscosity of ethylene polymers at 135 degrees Centigrade.
This is applicable to a wide spectrum of ethylene polymers having
densities from 0.910 to 0.970 g/cm2. Instructions are explained for
the determination of the viscosity ratio, inherent viscosity (also
referred to as the logarithmic viscosity number), and the limiting
viscosity number (intrinsic viscosity).
ASTM D4603-03 Standard
Test Method for Determining Inherent Viscosity of Polyethylene
Terephthalate (PET) by Glass Capillary Viscometer - This test
procedure is for the determination of the inherent viscosity of
polyethylene terephthalate (PET) soluble at 0.50 % concentration in
a 60/40 phenol/1,1,2,2-tetrachloroethane solution using a glass
capillary viscometer.
ASTM D1243-95 Standard
Test Method for Dilute Solution Viscosity of Vinyl Chloride Polymers
- This test procedure deals with the determination of the dilute
solution viscosity of vinyl chloride polymers in cyclohexanone. The
viscosity is expressed in terms of inherent viscosity (also referred
to as the logarithmic viscosity number).
ASTM D4001-93 Standard
Test Method for Determination of Weight-Average Molecular Weight of
Polymers By Light Scattering - This test procedure explains the test
methods for determining the weight-average molecular weight of
polymers by light scattering. It applies to all nonionic
homopolymers (branched or linear) that dissolve completely without
degradation or reaction to form stable solutions.
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